* Astronomy

Title: Carbon Dioxide in Exoplanetary Atmospheres: Rarely Dominant Compared to Carbon Monoxide and Water
Author: Kevin Heng, James R. Lyons

We present a comprehensive study of the abundance of carbon dioxide in exoplanetary atmospheres. We construct analytical models of systems in chemical equilibrium that include carbon monoxide, carbon dioxide, water, methane and acetylene and relate the equilibrium constants of the chemical reactions to temperature and pressure via the tabulated Gibbs free energies. We prove that such chemical systems may be described by a quintic equation for the mixing ratio of methane. By examining the abundances of these molecules across a broad range of temperatures (spanning equilibrium temperatures from 600 to 2500 K), pressures (via temperature-pressure profiles that explore albedo and opacity variations) and carbon-to-oxygen ratios (from 0.1 to 100), we conclude that carbon dioxide is subdominant compared to carbon monoxide and water. Atmospheric mixing does not alter this conclusion if carbon dioxide is subdominant everywhere in the atmosphere. Carbon dioxide and carbon monoxide may attain comparable abundances if the metallicity is greatly enhanced, but this property is negated by temperatures above 1000 K. For hydrogen-dominated atmospheres, our generic result has the implication that retrieval studies need to set the subdominance of carbon dioxide as a prior of the calculation and not let its abundance completely roam free as a fitting parameter, because it directly affects the inferred value of the carbon-to-oxygen ratio and may produce unphysical conclusions. We discuss the relevance of these implications for the hot Jupiter WASP-12b and suggest that some of the previous results are chemically impossible. The relative abundance of carbon dioxide to acetylene is potentially a sensitive diagnostic of the carbon-to-oxygen ratio.

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Title: Water Clouds in Y Dwarfs and Exoplanets
Author: Caroline V. Morley, Mark S. Marley, Jonathan J. Fortney, Roxana Lupu, Didier Saumon, Tom Greene, Katharina Lodders

The formation of clouds affects brown dwarf and planetary atmospheres of nearly all effective temperatures. Iron and silicate condense in L dwarf atmospheres and dissipate at the L/T transition. Minor species such as sulfides and salts condense in mid-late T dwarfs. For brown dwarfs below Teff=450 K, water condenses in the upper atmosphere to form ice clouds. Currently over a dozen objects in this temperature range have been discovered, and few previous theoretical studies have addressed the effect of water clouds on brown dwarf or exoplanetary spectra. Here we present a new grid of models that include the effect of water cloud opacity. We find that they become optically thick in objects below Teff=350-375 K. Unlike refractory cloud materials, water ice particles are significantly non-gray absorbers; they predominantly scatter at optical wavelengths through J band and absorb in the infrared with prominent features, the strongest of which is at 2.8 microns. H2O, NH3, CH4, and H2 CIA are dominant opacity sources; less abundant species such as may also be detectable, including the alkalis, H2S, and PH3. PH3, which has been detected in Jupiter, is expected to have a strong signature in the mid-infrared at 4.3 microns in Y dwarfs around Teff=450 K; if disequilibrium chemistry increases the abundance of PH3, it may be detectable over a wider effective temperature range than models predict. We show results incorporating disequilibrium nitrogen and carbon chemistry and predict signatures of low gravity in planetary- mass objects. Lastly, we make predictions for the observability of Y dwarfs and planets with existing and future instruments including the James Webb Space Telescope and Gemini Planet Imager.

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Title: Exoplanetary Atmospheres
Author: Nikku Madhusudhan (Cambridge), Heather Knutson (Caltech), Jonathan Fortney (UCSC), Travis Barman (U. Arizona)

The study of exoplanetary atmospheres is one of the most exciting and dynamic frontiers in astronomy. Over the past two decades ongoing surveys have revealed an astonishing diversity in the planetary masses, radii, temperatures, orbital parameters, and host stellar properties of exoplanetary systems. We are now moving into an era where we can begin to address fundamental questions concerning the diversity of exoplanetary compositions, atmospheric and interior processes, and formation histories, just as have been pursued for solar system planets over the past century. Exoplanetary atmospheres provide a direct means to address these questions via their observable spectral signatures. In the last decade, and particularly in the last five years, tremendous progress has been made in detecting atmospheric signatures of exoplanets through photometric and spectroscopic methods using a variety of space-borne and/or ground-based observational facilities. These observations are beginning to provide important constraints on a wide gamut of atmospheric properties, including pressure-temperature profiles, chemical compositions, energy circulation, presence of clouds, and non-equilibrium processes. The latest studies are also beginning to connect the inferred chemical compositions to exoplanetary formation conditions. In the present chapter, we review the most recent developments in the area of exoplanetary atmospheres. Our review covers advances in both observations and theory of exoplanetary atmospheres, and spans a broad range of exoplanet types (gas giants, ice giants, and super-Earths) and detection methods (transiting planets, direct imaging, and radial velocity). We close with a discussion of the bright prospects for future studies of exoplanetary atmospheres.

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Title: A simple, quantitative method to infer the minimum atmospheric height of small exoplanets
Authors: David M. Kipping, David S. Spiegel, Dimitar D. Sasselov

Amongst the many hundreds of transiting planet candidates discovered by the Kepler Mission, one finds a large number of candidates with sizes between that of the Earth and Neptune. The composition of these worlds is not immediately obvious with no Solar System analogue to draw upon and there exists some ambiguity as to whether a given candidate is a rocky Super-Earth or a gas-enveloped Mini-Neptune. The potential scientific value and observability of the atmospheres of these two classes of worlds varies significantly and given the sheer number of candidates in this size-range, there is evidently a need for a quick, simple metric to rank whether the planets have an extended atmosphere or not. In this work, we propose a way to calculate the 'minimum atmospheric height' (R_MAH) using only a planet's radius and mass as inputs. We assume and exploit the boundary condition that the bulk composition of a solid/liquid Super-Earth cannot be composed of a material lighter than that of water. Mass-radius loci above a pure-water composition planet correspond to R_MAH>0. The statistical confidence of a planet maintaining an extended atmosphere can be therefore easily calculated to provide a simple ranking of target planets for follow-up observations. We also discuss how this metric can be useful in the interpretation of the spectra of observed planetary atmospheres.

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