Title: Nature's Starships II: Simulating the Synthesis of Amino Acids in Meteorite Parent Bodies Author: Alyssa K. Cobb, Ralph E. Pudritz, Ben K. D. Pearce
Carbonaceous chondrite meteorites are known for having high water and organic material contents, including amino acids. Here we address the origin of amino acids in the warm interiors of their parent bodies (planetesimals) within a few million years of their formation, and connect this with the astrochemistry of their natal protostellar disks. We compute both the total amino acid abundance pattern as well as the relative frequencies of amino acids within the CM2 (e.g. Murchison) and CR2 chondrite subclasses based on Strecker reactions within these bodies. We match the relative frequencies to well within an order of magnitude among both CM2 and CR2 meteorites for parent body temperatures < 200°C. These temperatures agree with 3D models of young planetesimal interiors. We find theoretical abundances of approximately 7x105 parts-per-billion (ppb), which is in agreement with the average observed abundance in CR2 meteorites of 4±7x105, but an order of magnitude higher than the average observed abundance in CM2 meteorites of 2±2x104. We find that the production of hydroxy acids could be favoured over the production of amino acids within certain meteorite parent bodies (e.g. CI1, CM2) but not others (e.g. CR2). This could be due to the relatively lower NH3 abundances within CI1 and CM2 meteorite parent bodies, which leads to less amino acid synthesis. We also find that the water content in planetesimals is likely to be the main cause of variance between carbonaceous chondrites of the same subclass. We propose that amino acid abundances are primarily dependent on the ammonia and water content of planetesimals that are formed in chemically distinct regions within their natal protostellar disks.
Scientists at the Naval Research Laboratory are part of an international research team that is studying minerals formed during the early history of the solar system. Their goal is to learn more about the chemical and physical processes that occurred during the formation of the solar system. Their research was published in the May 2006 issue of Meteoritics and Planetary Science where a figure from the paper was selected as the cover image.
A 3-D tomographic reconstruction of a ~90-nm wide polyhedral serpentine grain from the Mighei CM carbonaceous chondrite meteorite. The surface of the tomogram is made semitransparent to visualise the interior. At the core is an elongated structure that extends the length of the grain. When viewed in axial orientation this structure is hollow from one end to the other, indicating that it is tubular. The tomogram was reconstructed from 120 bright-field images acquired over a tilt range of ± 60 degrees.
The researchers studied serpentine minerals in a group of primitive meteorites called CM carbonaceous chondrites. The CM carbonaceous chondrites formed over 4.5 billion years ago in the solar nebula, the cloud of gas and dust from which our sun and planets formed. Using a transmission electron microscope (TEM), the researchers imaged the three-dimensional structure of the serpentines and analysed their compositions. A TEM is capable of imaging the atomic structure of a material, and the research team needed its resolving power to analyse the serpentines, which are small, on the order of 90 nanometers (1 nanometer = 0.000000001 meter). Serpentines form by chemical reaction of anhydrous silicates (minerals that do not contain hydrogen) and water. The research team's findings reveal that the formation of these minerals occurred under oxygen-rich conditions, and suggest that the parent asteroids of the meteorites contained active hydrothermal systems that were capable of driving chemical reactions. Such reactions were likely similar to those that occur on Earth, but transpired over 4.5 billion years ago in space. Thomas Zega, who is the lead author on the paper, and Rhonda Stroud are researchers in NRL's Materials Science and Technology Division. The research team also includes members from Arizona State University, Eötvös L. University in Budapest, Hungary, and Utrecht University in The Netherlands.
Organic compounds in carbonaceous chondrites contain microscopic regions with surprising enrichments in the ratios of deuterium (D) to hydrogen (H) and nitrogen-15 (15N) to nitrogen-14 (14N). Henner Busemann and his colleagues Andrea Young, Conel Alexander, Sujoy Mukhopadhyay, and Larry Nittler at the Carnegie Institution of Washington, and Peter Hoppe (Max-Planck-Institut für Chemie, Mainz, Germany) demonstrate that organic matter resistant to dissolution by strong acids carry significant isotopic anomalies. They suggest that these anomalies most likely formed in interstellar space before the solar system formed and survived the long journey from molecular cloud to protostellar disk to asteroids.
A carbonaceous chondrite or a C-type chondrite is a type of chondritic meteorite which contains high levels of water and organic compounds, representing only a small proportion (~5%) of known meteorites. Their bulk composition is mainly silicates, oxides and sulphides, while the minerals olivine and serpentine are characteristic. The presence of volatile organic chemicals and water indicates that they have not undergone significant heating (greater than 200°C) since they formed, so their composition is considered to be representative of the solar nebula from which the solar system condensed.